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Route 5
Route5 map

Route 5 is located north of Saffron City/Route 6 (with underground passage to Vermilion City) and south of Cerulean City. The only thing of note here is the Day Care Centre, there is a PokeStop NPC here.

Catchable pokemon

C = Common U = Uncommon R = Rare VR = Very rare
D = Donator

M = Morning (04:00 to 09:59), D = Day (10:00 to 19:59), N = Night (20:00 to 03:59).

Walking

Rarity Pokémon When? Ev yield
C Bellsprout M-D Atk 1
C Pidgey M-D Spd 1
C Meowth N Spd 1
C Oddish N SpAtk 1
U Gloom N

SpAtk 2

? Togepi ? ?
VR Abra M-D-N SpAtk 1
D Shinx D Atk 1

Note that Meowth can learn Flash, Cut , Dig and Headbutt

There is one pokemon missing that IS NOT pineco

Trainers (Underground Passage)

Timothy Tangela lvl 17
Ponyta lvl 17
Chansey lvl 18